Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch.
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DOI: 10.1021/jacs.7b11180
Abstract: Ligand metathesis of Pd(II) complexes is mechanistically essential for cross-coupling. We present a study of halide→OH anion metathesis of (Ar)PdII complexes using vinylBPin as a bifunctional chemical probe with Pd(II)-dependent cross-coupling pathways. We identify the… read more here.
Keywords: bifunctional chemical; transmetalation; cross coupling; anion metathesis ... See more keywords