{Ge8[Fe(CO)4]8}7-: an anionic cubic germanium-iron-cluster featuring an unpaired electron.
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DOI: 10.1039/d2dt01090a
Abstract: Within the reaction of a metastable Ge(I)Cl solution and Na2Fe2(CO)8 the anionic cubic cluster compound {(thf)14Na6Ge8[Fe(CO)4]8}- (3) is obtained. The open shell character of 3 is proven by EPR spectroscopy. Quantum chemical calculations furthermore show… read more here.
Keywords: iron cluster; germanium iron; cubic germanium; cluster ... See more keywords