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Published in 2022 at "Journal of the American Society for Mass Spectrometry"
DOI: 10.1021/jasms.2c00070
Abstract: Negative-ion mode electrospray ionization of solutions of ethanol (RF0OH), 2-fluoroethanol (RF1OH), 2,2-difluoroethanol (RF2OH), and/or 2,2,2-trifluoroethanol (RF3OH) produces anionic dimers of the types (RFnO)2H- and (RFnO)(RFn+1O)H-. The exchange reactions of these anionic dimers with the neutral…
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Keywords:
anionic dimers;
fluorinated alcohols;
dimers fluorinated;