Investigating the Structure and Reactivity of Azolyl-Based Copper(I)–NHC Complexes: The Role of the Anionic Ligand
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.7b02737
Abstract: A family of copper(I)–NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial… read more here.
Keywords: anionic ligand; role anionic; role; azolyl ... See more keywords
Simultaneous Cationic and Anionic Ligand Exchange For Colloidally Stable CsPbBr3 Nanocrystals
Sign Up to like & getrecommendations! Published in 2019 at "ACS Energy Letters"
DOI: 10.1021/acsenergylett.9b00140
Abstract: Postsynthesis ligand exchange has been employed extensively on lead halide perovskite (LHP) nanocrystals (NCs), but the complex ligand shell composition of the starting NCs prevented a clear understanding of the exchange process, and the surface… read more here.
Keywords: exchange; cationic anionic; ligand; anionic ligand ... See more keywords
An anionic ligand snap-locks a long-range interaction in a magnesium-folded riboswitch
Sign Up to like & getrecommendations! Published in 2022 at "Nature Communications"
DOI: 10.1038/s41467-021-27827-y
Abstract: The archetypical transcriptional crcB fluoride riboswitch from Bacillus cereus is an intricately structured non-coding RNA element enhancing gene expression in response to toxic levels of fluoride. Here, we used single molecule FRET to uncover three… read more here.
Keywords: riboswitch; long range; ligand snap; range interaction ... See more keywords
An anionic-ligand installed pyrene-based MOF for the fluorescence detection of paraquat
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj05866a
Abstract: Paraquat is a highly toxic cationic agrochemical, and distinguishing it from other electron-deficient species is still a pending issue via fluorescence detection. In this work, taking advantage of the structural similarity, pyrene-based MOFs were applied… read more here.
Keywords: anionic ligand; fluorescence detection; pyrene based; paraquat ... See more keywords
Anionic ligand-induced chirality in perovskite nanoplatelets.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc05469h
Abstract: Perovskite materials passivated by chiral ligands have recently shown unique chiroptical activity with promising optoelectronic applications. However, the ligands have been limited to chiral amines. Here, chiral phosphate molecules have been exploited to synthesize CsPbBr3… read more here.
Keywords: ligand induced; perovskite nanoplatelets; induced chirality; anionic ligand ... See more keywords