Inter-ligand intramolecular through-space anisotropic shielding in a series of manganese carbonyl phosphorous compounds.
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DOI: 10.1039/c9dt03100f
Abstract: Eight novel manganese carbonyl complexes of the type [Mn(bpy-tBu)(CO)3PR3]+ (bpy-tBu = 4,4'-di-tert-butyl-2,2'-bipyridine; R = Cy, nBu, Me, p-tol, Ph, p-F-Ph, OEt, and OMe), have been synthesized and characterized by 1H NMR, FTIR, UV/Vis, HRMS and… read more here.
Keywords: inter ligand; anisotropic shielding; bpy tbu; series ... See more keywords