Enantioselective C–H Annulation of Indoles with Diazo Compounds through a Chiral Rh(III) Catalyst
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DOI: 10.1021/acscatal.7b00104
Abstract: The asymmetric C–H annulation of O-pivaloyl 1-indolehydroxamic acid with donor/acceptor diazo compounds has been achieved for the first time, to the best of our knowledge, by using a rhodium catalyst embedded in a chiral binaphthyl… read more here.
Keywords: annulation; indoles diazo; annulation indoles; diazo compounds ... See more keywords
Palladium-catalyzed sequential acylation/annulation of indoles with acyl chlorides using primary amine as the directing group
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DOI: 10.1039/d0nj04406g
Abstract: An efficient, palladium(ii)-catalyzed, C(sp2)–H acylation/annulation of indoles with acyl chlorides for the synthesis of substituted indolo[1,2-a]quinazolines is reported. read more here.
Keywords: annulation indoles; acyl chlorides; indoles acyl; palladium catalyzed ... See more keywords