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Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c01564
Abstract: Cesium carbonate-mediated stereoselective anomeric O-alkylation of a 2N,3O-oxazolidinone-protected d-mannosamine with sugar-derived primary or secondary alkyl triflates afforded the corresponding 2-amino-2-deoxy-β-d-mannosides in moderate to good yields and excellent stereoselectivity. The oxazolidinone ring can be opened with…
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Keywords:
anomeric alkylation;
oxazolidinone;
oxazolidinone protected;
synthesis ... See more keywords
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Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.8b03823
Abstract: Regio- and stereoselective synthesis of 1,2- cis-glycosides has been achieved by catalytic anomeric O-alkylation using organoboron compounds. Modulating steric and electronic factors of both catalysts and substrates enables activation of the axially oriented anomeric oxygens…
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Keywords:
anomeric alkylation;
cis glycosides;
synthesis cis;
stereoselective synthesis ... See more keywords