Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study
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DOI: 10.1021/acs.macromol.7b00853
Abstract: A series of allyl ansa-lanthanidocenes, [{Me2C(C5H4)(Flu)}Nd(1,3-C3H3(SiMe3)2)2]K (Flu = 9-fluorenyl; 1-Nd-K(allyl)) and {R2C(C5H4)(R′R′Flu)}Ln(1,3-C3H3(SiMe3)2)(THF)x (R = Me, R′ = 2,7-tBu2, Ln = Y (2-Y), Sc (2-Sc), x = 0; Ln = La (2-La), Pr (2-Pr), Nd (2-Nd),… read more here.
Keywords: substitution effects; allyl; ansa lanthanidocenes; single component ... See more keywords