Distal scaffold flexibility accelerates ligand substitution kinetics in manganese(I) tricarbonyls: flexible thianthrene versus rigid anthracene scaffolds.
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DOI: 10.1039/d2dt04048d
Abstract: This work investigates the effect of molecular flexibility on fundamental ligand substitution kinetics in a pair of manganese(I) carbonyls supported by scaffold-based ligands. In previous work, we reported that the planar and rigid, anthracene-based scaffold… read more here.
Keywords: py2; anth py2; ligand substitution; flexibility ... See more keywords