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Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00304
Abstract: Global consumption of triphenylphosphine (Ph3P) for phosphorus-mediated organic synthesis and production of the dead-end triphenylphosphine oxide (Ph3PO) waste is exceptionally high. Recycling Ph3PO and/or use of it as a reaction mediator gained significant attention. On…
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Keywords:
catalytic appel;
reaction;
appel reaction;
tio2 surface ... See more keywords
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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00738
Abstract: A method for the generation of trifluoromethylated β-keto diazos and their applications in intramolecular Appel type reactions are reported. The key success of this reaction is a diazo species as an N-nucleophile in Appel reactions.…
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Keywords:
trifluoromethylated keto;
reaction;
keto diazos;
intramolecular appel ... See more keywords