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Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b03427
Abstract: A phosphino-imidazoline (PHIM) ligand possessing axial chirality is prepared in a straightforward five-step synthesis. Configurational stability around the chiral axis is achieved by the diastereofacial π-stacking between the pentafluorophenyl and the naphthalene rings. In particular,…
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Keywords:
catalysis diastereofacial;
approach access;
ligand;
stacking approach ... See more keywords
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1
Published in 2020 at "Molecules"
DOI: 10.3390/molecules25030593
Abstract: A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available reagents (1,1,1-tris(4-hydroxyphenyl)ethane and chlorophosphines) is described. We have made use of this approach to prepare a small family of…
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Keywords:
trisphosphinite ligands;
access trimetallic;
versatile approach;
approach access ... See more keywords