Parallel Approaches for the Functionalization of Thietes: α-Metalation versus C-H Activation.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01961
Abstract: For the first time, an approach to 3,4-disubstituted thietes was developed through two complementary paths. While the first one relies on α-metalation, the second is based on direct C-H functionalization. A new library of sophisticated… read more here.
Keywords: approaches functionalization; metalation; parallel approaches; thietes metalation ... See more keywords
New approaches to the functionalization of the 1-carba-closo-decaborate anion.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06395b
Abstract: Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB9H10]- at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and… read more here.
Keywords: new approaches; closo decaborate; approaches functionalization; decaborate anion ... See more keywords