Born–Oppenheimer approximation in optical cavities: from success to breakdown†
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DOI: 10.1039/d0sc05164k
Abstract: The coupling of a molecule and a cavity induces nonadiabaticity in the molecule which makes the description of its dynamics complicated. For polyatomic molecules, reduced-dimensional models and the use of the Born–Oppenheimer approximation (BOA) may… read more here.
Keywords: approximation optical; born oppenheimer; optical cavities; cavities success ... See more keywords