Oxidative degradation of acetaminophen using superoxide ion generated in ionic liquid/aprotic solvent binary system
Sign Up to like & getrecommendations! Published in 2021 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2021.118730
Abstract: Abstract The environmental contamination by pharmaceuticals is on a continual rise, ensuing levels which are imminent globally. While the alleged harmful effects of drug waste are being rapidly substantiated at present, the development of effective… read more here.
Keywords: aprotic solvent; degradation acetaminophen; degradation; binary system ... See more keywords
Aromatic Bromination of N-Phenylacetamide Inside CNTs. Are CNTs Real Nanoreactors Controlling Regioselectivity and Kinetics? A QM/MM Investigation
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b07296
Abstract: We carried out a computational investigation on the mechanism of the bromination reaction of N-phenylacetamide inside CNTs, in water, and in an aprotic solvent (ethylbenzene). A full QM and a QM/MM approach was used. In… read more here.
Keywords: phenylacetamide inside; aprotic solvent; bromination; investigation ... See more keywords
Oxidative Rearrangement via 1,2-Aryl Migration using Hydroxy(tosyloxy)iodobenzene in a Polar Aprotic Solvent
Sign Up to like & getrecommendations! Published in 2020 at "Synlett"
DOI: 10.1055/s-0040-1708010
Abstract: A series of geminal β,β-ditosyloxy ketones were synthesized in moderate to good yields through hydroxy(tosyloxy)iodobenzene-mediated ditosyloxylation of readily accessible α,β-unsaturated ketones in a polar aprotic solvent. A mechanism has been proposed for the synthesis of… read more here.
Keywords: aprotic solvent; hydroxy tosyloxy; polar aprotic; tosyloxy iodobenzene ... See more keywords