Proton-coupled redox properties and water oxidation catalysis of an aqua-coordinated (µ-oxo)diruthenium(III) complex
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120007
Abstract: Abstract The electronic absorption and redox properties as well as the catalysis for water oxidation reaction (WOR) of an aqua-coordinated oxo-bridged diruthenium(III) complex trans(µ-O,OH2)-[Ru2(µ-O)(µ-CH3COO)2(bpy)2(H2O)2](PF6)2·3H2O ([1](PF6)2·3H2O; bpy = 2,2′-bipyridine) in aqueous media are reported. [1]2+ displays a visible… read more here.
Keywords: oxidation; aqua; water oxidation; redox properties ... See more keywords
Acid Catalysis in the Oxidation of Substrates by Mononuclear Manganese(III)-Aqua Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00430
Abstract: Acids are known to enhance the reactivities of metal-oxygen intermediates, such as metal-oxo, -hydroperoxo, -peroxo, and -superoxo complexes, in biomimetic oxidation reactions. Although metal-aqua (and metal-hydroxo) complexes have been shown to be potent oxidants in… read more here.
Keywords: acid catalysis; oxidation; aqua complexes; aqua ... See more keywords
Influence of Number of Ligands and Point Group on the Electronic Structure of Co2+ Aqua-Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02358
Abstract: The nucleation process of zeolitic imidazolate frameworks (ZIFs) is, to date, not yet completely understood, making the search for tailored materials very difficult. Recently, it has been shown that, during the formation process, the symmetry… read more here.
Keywords: number ligands; point group; aqua; electronic structure ... See more keywords
Hydroxylated Polyoxometalate with Cu(II)- and Cu(I)-Aqua Complexes: A Bifunctional Catalyst for Electrocatalytic Water Splitting at Neutral pH.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00423
Abstract: A sole inorganic framework material [Li(H2O)4][{CuI(H2O)1.5} {CuII(H2O)3}2{WVI12O36(OH)6}]·N2·H2S·3H2O (1) consisting of a hydroxylated polyoxometalate (POM) anion, {WVI12O36(OH)6}6-, a mixed-valent Cu(II)- and Cu(I)-aqua cationic complex species, [{CuI(H2O)1.5}{CuII(H2O)3}2]5+, a Li(I)-aqua complex cation, and three solvent molecules, has been… read more here.
Keywords: aqua; water; bifunctional catalyst; catalyst electrocatalytic ... See more keywords