Aquation and Anation Kinetics of Rhenium(I) Dicarbonyl Complexes: Relation to Cell Toxicity and Bioavailability.
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DOI: 10.1021/acs.inorgchem.0c02389
Abstract: The aquation reactions of four rhenium(I) dicarbonyl complexes, [Re(CO)2(NN)(PR3)(Cl)], where NN = 1,10-phenanthroline (Phen) and 2,9-dimethyl-1,10-phenanthroline (DMPhen) and PR3 = 1,3,5-triaza-7-phosphaadamantane (PTA) and 1,4-diacetyl-1,3,7-triaza-5-phosphabicylco[3.3.1]nonane (DAPTA). Additionally, the anation reactions of the corresponding aqua complexes with… read more here.
Keywords: rhenium dicarbonyl; aquation; anation; rate ... See more keywords
Acid Catalysis in the Oxidation of Substrates by Mononuclear Manganese(III)-Aqua Complexes.
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DOI: 10.1021/acs.inorgchem.2c00430
Abstract: Acids are known to enhance the reactivities of metal-oxygen intermediates, such as metal-oxo, -hydroperoxo, -peroxo, and -superoxo complexes, in biomimetic oxidation reactions. Although metal-aqua (and metal-hydroxo) complexes have been shown to be potent oxidants in… read more here.
Keywords: acid catalysis; oxidation; aqua complexes; aqua ... See more keywords