Articles with "aqueous redox" as a keyword



Phenothiazine-Based Organic Catholyte for High-Capacity and Long-Life Aqueous Redox Flow Batteries.

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Published in 2019 at "Advanced materials"

DOI: 10.1002/adma.201901052

Abstract: Redox-active organic materials have been considered as one of the most promising "green" candidates for aqueous redox flow batteries (RFBs) due to the natural abundance, structural diversity, and high tailorability. However, many reported organic molecules… read more here.

Keywords: aqueous redox; capacity; flow batteries; redox ... See more keywords

Aqueous Redox Flow Batteries: Small Organic Molecules for the Positive Electrolyte Species.

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Published in 2023 at "ChemSusChem"

DOI: 10.1002/cssc.202300303

Abstract: There are a number of critical requirements for electrolytes in aqueous redox flow batteries. This paper reviews organic molecules that have been used as the redox-active electrolyte for the positive cell reaction in aqueous redox… read more here.

Keywords: aqueous redox; redox flow; redox; organic molecules ... See more keywords

Constructing Hydrophilic Polymer Membranes with Microporosity for Aqueous Redox Flow Batteries.

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Published in 2025 at "ChemSusChem"

DOI: 10.1002/cssc.202402562

Abstract: Ion selective membranes (ISMs) are key components of aqueous redox flow batteries (ARFBs), and their property in selective ion transport largely determines the energy storage efficiency of ARFBs. Traditional ISMs are based on microphase-separated structures… read more here.

Keywords: flow batteries; polymer membranes; aqueous redox; redox flow ... See more keywords

Reduction potential tuning of first row transition metal MIII/MII (M = Cr, Mn, Fe, Co, Ni) hexadentate complexes for viable aqueous redox flow battery catholytes: A DFT study

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Published in 2017 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2017.05.199

Abstract: Abstract We systematically investigated the tuning of the reduction potentials ( E 0 ) for the first row transition metal (M = Cr, Mn, Fe, Co, Ni) complexes with the functionalized 1,4,7-Triazacyclononane-N,N',N”-triacetate (TCTA) ligands by means of… read more here.

Keywords: reduction; aqueous redox; group; flow battery ... See more keywords

Two-dimensional metal-organic framework nanosheets-modified porous separator for non-aqueous redox flow batteries

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Published in 2020 at "Journal of Membrane Science"

DOI: 10.1016/j.memsci.2020.118463

Abstract: Abstract Non-aqueous redox flow batteries (NARFBs) are promising for large-scale energy storage. However, the lack of high performance membrane is still impeding their further development. Two-dimensional (2D) metal-organic framework (MOF) nanosheets-modified porous separators are prepared… read more here.

Keywords: separator; non aqueous; aqueous redox; flow batteries ... See more keywords
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Bis(diisopropylamino)cyclopropenium-arene Cations as High Oxidation Potential and High Stability Catholytes for Non-aqueous Redox Flow Batteries.

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Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.0c07464

Abstract: This Article describes the development of 1,2-bis(diisopropylamino)-3-cyclopropenylium-functionalized (DAC-functionalized) benzene derivatives as high-potential catholytes for non-aqueous redox flow batteries. Density functional theory (DFT) calculations predict that the oxidation potentials (in CH3CN) of various DAC-benzene derivatives will… read more here.

Keywords: non aqueous; aqueous redox; bis diisopropylamino; redox flow ... See more keywords

Screening Ultra-Stable (Phenazine)dioxyalkanocic Acids with Varied Water-Solubilizing Chain Lengths for High-Capacity Aqueous Redox Flow Batteries.

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.3c11887

Abstract: Aqueous redox flow batteries (ARFBs) hold great potential for large-scale energy storage. Recently, research on aqueous flow batteries has shifted toward water-soluble organic molecules with redox capabilities to reduce the use of mineral resources. The… read more here.

Keywords: redox; capacity; flow batteries; aqueous redox ... See more keywords

Critical Roles of pH and Activated Carbon on the Speciation and Performance of an Archetypal Organometallic Complex for Aqueous Redox Flow Batteries.

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.3c13828

Abstract: A lack of suitable high-potential catholytes hinders the development of aqueous redox flow batteries (RFBs) for large-scale energy storage. Hydrolysis of the charged (oxidized) catholyte typically occurs when its redox potential approaches that of water,… read more here.

Keywords: redox flow; performance; flow batteries; aqueous redox ... See more keywords

Mono-methyl viologen: A promising anolyte for alkaline aqueous redox flow batteries

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Published in 2024 at "Journal of Materials Chemistry A"

DOI: 10.1039/d4ta03959a

Abstract: An Aqueous Redox Flow Battery (ARFB) emerges as a sustainable option for large-scale energy storage systems due to its relatively low cost and abundant raw materials. However, there exists a... read more here.

Keywords: mono methyl; redox flow; methyl viologen; aqueous redox ... See more keywords