Articles with "aqueous redox" as a keyword



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Phenothiazine-Based Organic Catholyte for High-Capacity and Long-Life Aqueous Redox Flow Batteries.

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Published in 2019 at "Advanced materials"

DOI: 10.1002/adma.201901052

Abstract: Redox-active organic materials have been considered as one of the most promising "green" candidates for aqueous redox flow batteries (RFBs) due to the natural abundance, structural diversity, and high tailorability. However, many reported organic molecules… read more here.

Keywords: aqueous redox; capacity; flow batteries; redox ... See more keywords
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Aqueous Redox Flow Batteries: Small Organic Molecules for the Positive Electrolyte Species.

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Published in 2023 at "ChemSusChem"

DOI: 10.1002/cssc.202300303

Abstract: There are a number of critical requirements for electrolytes in aqueous redox flow batteries. This paper reviews organic molecules that have been used as the redox-active electrolyte for the positive cell reaction in aqueous redox… read more here.

Keywords: aqueous redox; redox flow; redox; organic molecules ... See more keywords
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Reduction potential tuning of first row transition metal MIII/MII (M = Cr, Mn, Fe, Co, Ni) hexadentate complexes for viable aqueous redox flow battery catholytes: A DFT study

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Published in 2017 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2017.05.199

Abstract: Abstract We systematically investigated the tuning of the reduction potentials ( E 0 ) for the first row transition metal (M = Cr, Mn, Fe, Co, Ni) complexes with the functionalized 1,4,7-Triazacyclononane-N,N',N”-triacetate (TCTA) ligands by means of… read more here.

Keywords: reduction; aqueous redox; group; flow battery ... See more keywords
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Two-dimensional metal-organic framework nanosheets-modified porous separator for non-aqueous redox flow batteries

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Published in 2020 at "Journal of Membrane Science"

DOI: 10.1016/j.memsci.2020.118463

Abstract: Abstract Non-aqueous redox flow batteries (NARFBs) are promising for large-scale energy storage. However, the lack of high performance membrane is still impeding their further development. Two-dimensional (2D) metal-organic framework (MOF) nanosheets-modified porous separators are prepared… read more here.

Keywords: separator; non aqueous; aqueous redox; flow batteries ... See more keywords
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Bis(diisopropylamino)cyclopropenium-arene Cations as High Oxidation Potential and High Stability Catholytes for Non-aqueous Redox Flow Batteries.

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Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.0c07464

Abstract: This Article describes the development of 1,2-bis(diisopropylamino)-3-cyclopropenylium-functionalized (DAC-functionalized) benzene derivatives as high-potential catholytes for non-aqueous redox flow batteries. Density functional theory (DFT) calculations predict that the oxidation potentials (in CH3CN) of various DAC-benzene derivatives will… read more here.

Keywords: non aqueous; aqueous redox; bis diisopropylamino; redox flow ... See more keywords