A short synthesis of protected 3-deoxy-d-arabino-2-heptulosonates (DAH) from shikimic acid based on silyl group migration
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DOI: 10.1016/j.tetlet.2018.11.045
Abstract: Abstract The reaction of (2 S ,3 S ,4 R )-2,3,4,7-tetrahydroxy-6-oxoheptanals with lower alcohols produced protected 3-deoxy- d - arabino -2-heptulosonates. The key transformation is based on an 1,4-O–O silyl group migration, followed by 6-… read more here.
Keywords: arabino heptulosonates; group migration; deoxy arabino; silyl group ... See more keywords