Metal Coordination Induces Phase Segregation in Amphipolar Arborescent Copolymers with a Core–Shell–Corona Architecture
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DOI: 10.1021/acs.macromol.0c00778
Abstract: Arborescent copolymers with a core–shell–corona (CSC) architecture were synthesized and the topology of the molecules was challenged (constrained) through intramolecular interactions, resulting in phase separation breaking the symmetry of radial density. The inner poly(2-vinylpyridine) shell… read more here.
Keywords: phase segregation; arborescent copolymers; copolymers core; shell ... See more keywords
Unimolecular Micelles from Randomly Grafted Arborescent Copolymers with Different Core Branching Densities: Encapsulation of Doxorubicin and In Vitro Release Study
Sign Up to like & getrecommendations! Published in 2023 at "Materials"
DOI: 10.3390/ma16062461
Abstract: A series of amphiphilic arborescent copolymers of generations G1 and G2 with an arborescent poly(γ-benzyl L-glutamate) (PBG) core and poly(ethylene oxide) (PEO) chain segments in the shell, PBG-g-PEO, were synthesized and evaluated as drug delivery… read more here.
Keywords: branching densities; core; unimolecular micelles; pbg ... See more keywords