Three-Dimensional Supramolecular Architectures with MnII Ions Assembled from Hydrogen Bonding Interactions: Crystal Structures and Antiferromagnetic Properties
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DOI: 10.1021/acsomega.1c05285
Abstract: Two novel cocrystal MnII compounds were successfully synthesized. The composition of two kinds crystals correspond to [Mn(hfac)2La2·Mn(hfac)2La(H2O)·Mn(hfac)2(H2O)2] (1) and [Mn(hfac)2Lb2·Mn(hfac)2(H2O)2·0.5(C6H14)] (2) [La = 1,3-bis(1′-oxyl-3′-oxido-4′,4′,5′,5′-tetramethyl-4,5-dihydro-1H-imidazol-2-y1)benzene; Lb = 1-(1′-oxyl-4′,4′,5′,5′-tetramethylimidazolin-2-yl)-3-(1′-oxyl-3′-oxo-4′,4′,5′,5′-tetramethylimidazolin-2-yl)benzene; hfac = hexafluoroacetylacetonato). Surprisingly, the compounds were not… read more here.
Keywords: hfac; mnii ions; architectures mnii; three dimensional ... See more keywords