trans-Selective and Switchable Arene Hydrogenation of Phenol Derivatives
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DOI: 10.1021/acscatal.0c03423
Abstract: A trans-selective arene hydrogenation of abundant phenol derivatives catalyzed by a commercially available heterogeneous palladium catalyst is reported. The described method tolerates a variety of functional groups and provides access to a broad scope of… read more here.
Keywords: trans selective; phenol derivatives; selective switchable; hydrogenation ... See more keywords
Rh(CAAC)-Catalyzed Arene Hydrogenation: Evidence for Nanocatalysis and Sterically Controlled Site-Selective Hydrogenation
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DOI: 10.1021/acscatal.8b02589
Abstract: We report the arene hydrogenation of ethers, amides, and esters at room temperature and low hydrogen pressure, starting from [(CAAC)Rh(COD)Cl] (CAAC = cyclic alkyl amino carbene). Kinetic, mechanistic, and Rh K-edge XAFS studies showed formation… read more here.
Keywords: site selective; hydrogenation; caac cod; arene hydrogenation ... See more keywords