Arene-perfluoroarene interaction induced chiroptical inversion and precise ee% detection of chiral acids in a benzimidazole-involved ternary coassembly.
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr06254a
Abstract: Flexible regulation of chirality and handedness of chiral functional materials and quantitative sensing of natural chiral compounds remains a considerable challenge. Herein, an achiral fluorescent 1-pyrenecarboxylic acid-benzimidazole derivative (PBI) was synthesized and its chiroptical properties… read more here.
Keywords: chiral acids; interaction; induced chiroptical; arene perfluoroarene ... See more keywords
Nanosegregation in arene-perfluoroarene π-systems for hybrid layered Dion–Jacobson perovskites
Sign Up to like & getrecommendations! Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr08311b
Abstract: Layered hybrid perovskites are based on organic spacers separating hybrid perovskite slabs. We employ arene and perfluoroarene moieties based on 1,4-phenylenedimethylammonium (PDMA) and its perfluorinated analogue (F-PDMA) in the assembly of hybrid layered Dion–Jacobson perovskite… read more here.
Keywords: hybrid layered; layered dion; dion jacobson; arene perfluoroarene ... See more keywords
Arene–perfluoroarene interactions confer enhanced mechanical properties to synthetic nanotubes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc05932g
Abstract: Supramolecular nanotubes prepared through macrocycle assembly offer unique properties that stem from their long-range order, structural predictability, and tunable microenvironments. However, assemblies that rely on weak non-covalent interactions often have limited aspect ratios and poor… read more here.
Keywords: interactions confer; confer enhanced; enhanced mechanical; arene perfluoroarene ... See more keywords
Influence of the Arene/Perfluoroarene Ratio on the Structure and Non-Covalent Interactions in Crystals of Cd(II), Cd(II)-Tb(III) and Cu(II) Compounds
Sign Up to like & getrecommendations! Published in 2023 at "Crystals"
DOI: 10.3390/cryst13040678
Abstract: The influence of arene/perfluoroarene ratio on the structure and crystal packing of carboxylate and nitrate-carboxylate complexes of Cd, Cd-Tb and Cu was studied, using the following compounds: pentafluorobenzoate (pfb) and 4-allyl-2,3,5,6-tetrabenzoate (Afb) anions and 1,10-phenanthroline… read more here.
Keywords: phen; influence arene; non covalent; arene perfluoroarene ... See more keywords