Comprehensive Experimental and Computational Study of η6-Arene Ruthenium(II) and Osmium(II) Complexes Supported by Sulfur Analogues of the β-Diketiminate Ligand
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DOI: 10.1021/acs.organomet.8b00111
Abstract: In comparison to β-diketiminates, a highly exploited class of N,N-chelating ligands, the corresponding β-thioketoiminates, monothio-substituted analogues, have received only minor attention. β-Thioketoiminates are straightforwardly prepared through treatment of an appropriate β-ketoiminate with Lawesson’s reagent. Employing… read more here.
Keywords: complexes supported; comprehensive experimental; computational study; study arene ... See more keywords
Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications
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DOI: 10.3390/inorganics6030097
Abstract: The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed… read more here.
Keywords: ru4 cymene; metalla; metalla assemblies; anthracene moieties ... See more keywords
Arene-Ruthenium(II) Complexes with Carbothiamidopyrazoles as a Potential Alternative for Antibiotic Resistance in Human
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DOI: 10.3390/molecules27020468
Abstract: To meet the demand for alternatives to commonly used antibiotics, this paper evaluates the antimicrobial potential of arene-ruthenium(II) complexes and their salts, which may be of value in antibacterial treatment. Their antimicrobial activity (MIC, MBC/MFC)… read more here.
Keywords: ruthenium complexes; carbothiamidopyrazoles potential; arene ruthenium; complexes carbothiamidopyrazoles ... See more keywords