Mechanistic Investigations on N-Cα Bond Cleavages in Dibasic Peptides Containing Internal Lys and Arg Residues.
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DOI: 10.1021/jasms.2c00055
Abstract: The model nonapeptide AAARAAKAG* (* indicates amide) is used to explore N-Cα bond fragmentation under CID-MS conditions. Neighboring group participation and the effect of positioning of Lys and Arg residues on N-Cα bond cleavage is… read more here.
Keywords: arg residues; arg; mechanistic investigations; lys arg ... See more keywords