Investigation of microstructure in poly(methyl methacrylate) prepared via ambient temperature ARGET-ATRP: a combined approach of 1D and 2D NMR spectroscopy
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Polymer Research"
DOI: 10.1007/s10965-020-02153-x
Abstract: This investigation reports the analysis of different microstructures present in poly(methyl methacrylate) (PMMA) using1D and 2D NMR spectroscopy. The PMMA used in this study has been prepared via activators regenerated by electron transfer atom transfer… read more here.
Keywords: nmr spectroscopy; methyl methacrylate; arget atrp; poly methyl ... See more keywords
Tin(II) 2-ethylhexanoate and ascorbic acid as reducing agents in solution ARGET ATRP: A kinetic study approach by mathematical modeling and simulation
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.01.123
Abstract: Abstract The mechanism of activators regenerated by electron transfer (ARGET) associated with atom transfer radical polymerization (ATRP) has attracted attention because of the transition metal catalyst reduction in the conventional ATRP process. In this paper,… read more here.
Keywords: reducing agents; solution arget; tin ethylhexanoate; ethylhexanoate ascorbic ... See more keywords
ARGET-ATRP synthesis and swelling response of compositionally varied poly(methacrylic acid-co-N,N-diethylaminoethyl methacrylate) polyampholyte brushes.
Sign Up to like & getrecommendations! Published in 2018 at "Soft matter"
DOI: 10.1039/c8sm00882e
Abstract: Modifying the composition of polyampholytes, which are comprised of charge-positive and charge-negative repeat units, directly contributes to trade-offs between charge and structure, which are externally regulated by solution pH and added salt. Here, the relative… read more here.
Keywords: poly methacrylic; polyampholyte brushes; acid diethylaminoethyl; methacrylic acid ... See more keywords
Highly-reactive haloester surface initiators for ARGET ATRP readily prepared by radio frequency glow discharge plasma.
Sign Up to like & getrecommendations! Published in 2019 at "Biointerphases"
DOI: 10.1116/1.5110163
Abstract: New surface initiators for ARGET ATRP (activators regenerated by electron transfer atomic transfer radical polymerization) have been prepared by the plasma deposition of haloester monomers. Specifically, methyl 3-bromopropionate (M3BP), methyl 2-chloropropionate, and ethyl 2-fluoropropionate (E2FP)… read more here.
Keywords: surface initiators; plasma; arget atrp; initiators arget ... See more keywords
Ethyl Lactate, a New Green Solvent for ARGET ATRP of Methyl Acrylate
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry Letters"
DOI: 10.1246/cl.170107
Abstract: The use of ethyl lactate solvent in the activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) of methyl acrylate is demonstrated. The solvent has good solubility for both polymers and monomers and… read more here.
Keywords: ethyl lactate; methyl acrylate; arget atrp; atrp methyl ... See more keywords