Unmasking the Iron–Oxo Bond of the [(Ligand)Fe-OIAr]2+/+ Complexes
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DOI: 10.1021/jasms.2c00094
Abstract: ArIO (ArI = 2-(tBuSO2)C6H4I) is an oxidant used to oxidize FeII species to their FeIV-oxo state, enabling hydrogen-atom transfer (HAT) and oxygen-atom transfer (OAT) reactions at low energy barriers. ArIO, as a ligand, generates masked… read more here.
Keywords: iron oxo; tpa; ligand; ario ... See more keywords