Transition-Metal-Free Cleavage of C-C Triple Bonds in Aromatic Alkynes with S8 and Amides Leading to Aryl Thioamides.
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DOI: 10.1021/acs.orglett.8b00573
Abstract: A novel transition-metal-free cleavage reaction of C-C triple bonds in aromatic alkynes with S8 and amides furnishes aryl thioamides in moderate to excellent yields. The remarkable features of this thioamidation include the metal-free cleavage of… read more here.
Keywords: free cleavage; transition metal; aromatic alkynes; triple bonds ... See more keywords