Determination of phthalate esters in airborne particulates by heterogeneous photo-Fenton catalyzed aromatic hydroxylation fluorimetry.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of hazardous materials"
DOI: 10.1016/j.jhazmat.2016.10.055
Abstract: The environmental contaminants phthalic acid esters (PAEs) were determined by aromatic hydroxylation fluorimetry combined with heterogeneous photo-Fenton process in the presence of vermiculite supported BiFeO3 (VMT-BiFeO3). In strong alkaline solution, PAEs were hydrolyzed into phthalates… read more here.
Keywords: heterogeneous photo; photo fenton; aromatic hydroxylation; airborne particulates ... See more keywords
Understanding the Regioselectivity of Aromatic Hydroxylation over Divanadium-Substituted γ-Keggin Polyoxotungstate
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DOI: 10.1021/acscatal.7b02694
Abstract: The aromatic hydroxylation of pseudocumene (PC) with aqueous hydrogen peroxide catalyzed by the divanadium-substituted γ-Keggin polyoxotungstate TBA4[γ-PW10O38V2(μ-O)(μ-OH)] (TBA-1H, TBA = tetrabutylammonium) has been studied using kinetic modeling and DFT calculations. This reaction features high chemoselectivity… read more here.
Keywords: keggin polyoxotungstate; divanadium substituted; aromatic hydroxylation; regioselectivity ... See more keywords
Theoretical study of aromatic hydroxylation of the [Cu2(H-XYL)O2]2+ complex mediated by a side-on peroxo dicopper core and Cu-ligand effects.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02814e
Abstract: In this work, the aromatic hydroxylation mechanism of the [Cu2(H-XYL)O2]2+ complex mediated by a peroxo dicopper core and Cu-ligand effects are investigated by using hybrid density functional theory (DFT) and the broken symmetry B3LYP method.… read more here.
Keywords: xyl complex; hydroxylation; aromatic hydroxylation; ligand ... See more keywords