Nickel‐Catalyzed Hydrophosphonylation and Hydrogenation of Aromatic Nitriles Assisted by Lewis Acid
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DOI: 10.1002/cctc.201801989
Abstract: In this paper, we describe the catalytic hydrophosphonylation of several aromatic nitriles used to synthesize α‐aminophosphonates (α‐APs) using commercially available trialkyl phosphites (P(OR)3, R=Et, iPr, Bu,) and simple and inexpensive nickel chloride (NiCl2.6H2O) as the… read more here.
Keywords: aromatic nitriles; lewis acid; hydrophosphonylation hydrogenation; catalyzed hydrophosphonylation ... See more keywords
Iron-Promoted Decarboxylation of Arylacetic Acids for the Synthesis of Aromatic Nitriles with Sodium Nitrite as the Nitrogen Source
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DOI: 10.1055/s-0040-1707300
Abstract: A new and effective method was developed for the synthesis of aromatic nitriles from arylacetic acids by using NaNO2 as the nitrogen source and Fe(OTf)3 as the promoter at 50 °C. A series of arylacetic… read more here.
Keywords: aromatic nitriles; synthesis aromatic; nitrogen source; arylacetic acids ... See more keywords
The Active Chlorine Mediated Electrochemical Synthesis of Aromatic Nitriles through Cascade Reaction
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DOI: 10.1149/1945-7111/ad6b47
Abstract: An efficient and transition-metal-free synthesis strategy of aromatic nitriles from corresponding aldehydes with H2SO4(NH2OH)2 as the nitrogen source and Cl-/ClO- as the redox mediator was developed. The redox Cl-/ClO- showed electrochemical reversibility in acidic condition.… read more here.
Keywords: aromatic nitriles; chlorine mediated; synthesis; active chlorine ... See more keywords
Acetylene-driven superbase-mediated self-organization of (het)arylpyridines from (het)aromatic nitriles
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DOI: 10.71267/mencom.7801
Abstract: Acetylene gas reacts with (het)aromatic nitriles in the KOH/DMSO/MeOH superbase composition at 90 °C for 10 min to afford 2-(het)arylpyridines in up to 36 read more here.
Keywords: acetylene driven; aromatic nitriles; superbase; het aromatic ... See more keywords