On-Surface Formation of a Transient Corrole Radical and Aromaticity-Driven Interfacial Electron Transfer
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c04451
Abstract: Corroles on metal surfaces show substantial reactivity and aromaticity-driven interfacial electron transfer of their transient σ/π-radicals. These effects are much more pronounced than for the clos... read more here.
Keywords: driven interfacial; interfacial electron; electron transfer; aromaticity driven ... See more keywords
Aromaticity-Driven Access to Cycloalkyl-Fused Naphthalenes.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01220
Abstract: We report the efficient synthesis of cycloalkyl-fused naphthalenes through the [4 + 2]-cycloaddtion/decarboxylative aromatization of alkyne-tethered aryne insertion adducts. These scaffolds were difficult to synthesize using conventional reactions. The reaction proceeds via the formation of… read more here.
Keywords: driven access; cycloalkyl fused; access cycloalkyl; aromaticity driven ... See more keywords