Artificial water-soluble systems inspired by [FeFe]-hydrogenases for electro- and photocatalytic hydrogen production
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.11.206
Abstract: Abstract [FeFe]-hydrogenases efficiently catalyze the hydrogen evolution reactions (HERs) at rates of up to 104 s−1 with low overpotentials in aqueous media. Although the small-molecule diiron mimetics of the active site of [FeFe]-hydrogenases have been… read more here.
Keywords: fefe hydrogenases; systems inspired; water soluble; soluble systems ... See more keywords
Bilayer versus Polymeric Artificial Water Channel Membranes: Structural Determinants for Enhanced Filtration Performances.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c07425
Abstract: Artificial water channels (AWCs) and their natural aquaporin counterparts selectively transport water. They represent a tremendous source of inspiration to devise biomimetic membranes for several applications, including desalination. They contain variable water-channel constructs with adaptative… read more here.
Keywords: water permeability; water; channel; performances bilayer ... See more keywords
Imidazole derivatives as artificial water channel building-blocks: structural design influence on water permeability.
Sign Up to like & getrecommendations! Published in 2018 at "Faraday discussions"
DOI: 10.1039/c8fd00024g
Abstract: A series of mono- and di-ureidoethylimidazole derivatives were tested as self-assembled supramolecular channels for water transport. Several structural behaviours were compared in order to gain insight on the structure-water transport activity relationship. The three main… read more here.
Keywords: building blocks; water; channel building; water channel ... See more keywords
Artificial water channels: inspiration, progress, and challenges.
Sign Up to like & getrecommendations! Published in 2018 at "Faraday discussions"
DOI: 10.1039/c8fd00132d
Abstract: This article is based on the concluding remarks made in the Faraday Discussion Meeting on Artificial Water Channels. read more here.
Keywords: progress challenges; inspiration progress; channels inspiration; water channels ... See more keywords
Oriented chiral water wires in artificial transmembrane channels
Sign Up to like & getrecommendations! Published in 2018 at "Science Advances"
DOI: 10.1126/sciadv.aao5603
Abstract: Chiral dipolar oriented water wires are observed inside artificial water channels embedded in supported bilayer membranes. Aquaporins (AQPs) feature highly selective water transport through cell membranes, where the dipolar orientation of structured water wires spanning… read more here.
Keywords: water; water channels; dipolar oriented; water wires ... See more keywords
Fluorofoldamer-Based Salt- and Proton-Rejecting Artificial Water Channels for Ultrafast Water Transport.
Sign Up to like & getrecommendations! Published in 2022 at "Nano letters"
DOI: 10.26434/chemrxiv-2022-mvdk0
Abstract: Here, we report on a novel class of fluorofoldamer-based artificial water channels (AWCs) that combines excellent water transport rate and selectivity with structural simplicity and robustness. Produced by a facile one-pot copolymerization reaction under mild… read more here.
Keywords: water; artificial water; water transport; fluorofoldamer based ... See more keywords