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Published in 2020 at "ChemMedChem"
DOI: 10.1002/cmdc.202000138
Abstract: A series of N- aryl and N- alkyl substituted imidazoles were synthesized and complexed with Ag + to obtain silver-NHC complexes of the form [Ag(NHC)2 ]X. These silver-NHC complexes were tested in-vitro versus the human…
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Keywords:
alkyl substituted;
cell lines;
myeloid leukemia;
aryl alkyl ... See more keywords
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Published in 2019 at "Carbohydrate research"
DOI: 10.1016/j.carres.2019.02.004
Abstract: Six different types of O-benzyl protected proline derivatives have been synthesized from D-glycals and 2C-formyl-glycals. One of the di-O-benzyl protected proline derivatives has been utilized for the synthesis of polysubstituted pyrrolizidines via [3 + 2] cycloaddition in…
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Keywords:
synthesis polysubstituted;
synthesis;
proline derivatives;
aryl alkyl ... See more keywords
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Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01758
Abstract: A transition-metal-free protocol capable of synthesizing diarylated aniline derivatives is reported. This method could be further employed to prepare aryl alkyl ethers. A wide range of thioethers, anilines, as well as alcohols were tolerated thanks…
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Keywords:
alkyl thioethers;
amination etherification;
nucleophilic amination;
aryl alkyl ... See more keywords
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Published in 2023 at "ACS chemical neuroscience"
DOI: 10.1021/acschemneuro.3c00030
Abstract: The complex and multifaceted nature of Alzheimer's disease has brought about a pressing demand to develop ligands targeting multiple pathways to combat its outrageous prevalence. Embelin is a major secondary metabolite of Embelia ribes Burm…
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Keywords:
amine hybrids;
alzheimer disease;
alkyl amine;
embelin aryl ... See more keywords
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Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01052
Abstract: The emergence of bacterial resistance and hesitance in approving new drugs has bolstered research on membrane-active agents such as antimicrobial peptides and their synthetic derivatives as therapeutic alternatives against bacterial infections. Herein, we document the…
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Keywords:
aryl alkyl;
lysines interact;
anionic lipid;
interact anionic ... See more keywords
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Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01172
Abstract: A one-pot synthesis of 2-(het)aryl/alkyl-3-cyanobenzofurans has been reported. The overall sequence involves base-induced reaction of 2-(2-bromoaryl)-3-(het)aryl-3-(methylthio)acrylonitriles with benzyl carbamate, generating α-(het)aroyl-α-(2-bromoaryl)acetonitriles, which are in situ subjected to copper-catalyzed intramolecular O-arylation, furnishing the 2-(het)aryl/alkyl-3-cyanobenzofurans in high…
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Keywords:
bromoaryl het;
aryl alkyl;
het aryl;
aryl ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13342
Abstract: Catalytic activation of unstrained and nonpolar C-C bonds remains a largely unmet challenge. Here, we describe our detailed efforts in developing a rhodium-catalyzed hydrogenolysis of unstrained C(aryl)-C(alkyl) bonds in 2,2'-methylenediphenols aided by removable directing groups.…
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Keywords:
unstrained aryl;
activation unstrained;
bonds methylenediphenols;
aryl alkyl ... See more keywords
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Published in 2017 at "MedChemComm"
DOI: 10.1039/c6md00589f
Abstract: Due to emerging resistance there is a steady need for new antimalarial drugs. Here, we report a new class of water soluble, non-toxic compounds, aryl-alkyl-lysines, with promising activity against the ring stage of Plasmodium falciparum.…
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Keywords:
aryl alkyl;
small molecular;
molecular membrane;
alkyl lysines ... See more keywords
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Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00240e
Abstract: Photo-induced radical reductive dehalogenation of inactivated aryl/alkyl bromides and chlorides with a palladium complex is described. Reductive cyclization, dehalogenative deuteration, and radical addition process can be achieved smoothly.
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Keywords:
palladium complex;
visible light;
aryl alkyl;
inactivated aryl ... See more keywords
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Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/c9qo01438a
Abstract: Cleavage of the C(aryl)–C(alkyl) σ-bond is important both in academy and industry as it holds the potential to provide straightforward access to a variety of targets from readily available chemical feedstocks such like alkylarenes. However,…
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Keywords:
recent progress;
cleavage;
aryl alkyl;
alkyl bond ... See more keywords
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Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj00383b
Abstract: Two novel Zn(II)-phthalocyanines having: (i) aryl azide (3) and (ii) alkyl azide (7) functional groups at the peripheral positions have been designed/synthesized for hydrogen sulfide (H2S) sensing purposes, and their photocharacteristic properties were investigated in…
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Keywords:
tetra substituted;
detection;
aryl alkyl;
phthalocyanines tetra ... See more keywords