A mild copper catalyzed method for the selective deprotection of aryl allyl ethers
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DOI: 10.1016/j.tetlet.2016.11.084
Abstract: Copper boryl reagents enable the selective cleavage of aryl allyl ethers to the corresponding phenols in good to moderate yields. read more here.
Keywords: mild copper; aryl allyl; allyl ethers;
Overcoming the Deallylation Problem: Palladium(II)-Catalyzed Chemo-, Regio-, and Stereoselective Allylic Oxidation of Aryl Allyl Ether, Amine, and Amino Acids.
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DOI: 10.1021/acs.orglett.0c02465
Abstract: We report herein a Pd(II)/bis-sulfoxide-catalyzed intramolecular allylic C-H acetoxylation of aryl allyl ether, amine, and amino acids with the retention of a labile allyl moiety. Mechanistically, the reaction proceeds through a distinct double-bond isomerization from… read more here.
Keywords: aryl allyl; allyl ether; amino acids; amine amino ... See more keywords