Site-Selective Functionalization of Polydopamine Films via Aryl Azide-Based Photochemical Reaction
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DOI: 10.1007/s13233-020-8083-3
Abstract: Although the post functionalization of versatile polydopamine (pD) films enables the expression of functional groups of interest on target substrates, their immobilization generally lacks site-selectivity within a surface platform. In this paper, we report a… read more here.
Keywords: site selective; functionalization; aryl azide; polydopamine films ... See more keywords
Tris(4-azidophenyl)methanol – a novel and multifunctional thiol protecting group
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DOI: 10.1039/d2ra05997e
Abstract: The novel tris(4-azidophenyl)methanol, a multifunctionalisable aryl azide, is reported. The aryl azide can be used as a protecting group for thiols in peptoid synthesis and can be cleaved under mild reaction conditions via a Staudinger… read more here.
Keywords: tris azidophenyl; protecting group; azidophenyl methanol; aryl azide ... See more keywords
A simple method to modulate the selectivity of aryl azide photolysis using cucurbit[8]uril.
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DOI: 10.1039/d4cc04209c
Abstract: Photolysis of aryl azides typically involves multiple reaction pathways. This study designed and synthesized an aryl azide rotamer with two conformations. In aqueous media, its photolysis yields two main products. However, when stabilized in one… read more here.
Keywords: method modulate; cucurbit uril; photolysis; aryl azide ... See more keywords