Reactivity of (NNN)-pincer nickel(II) aryl complex towards oxidative carbon-heteroatom bond formation
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron"
DOI: 10.1016/j.tet.2018.04.029
Abstract: Abstract The reactivity of an (NNN)-Ni(II) aryl complex towards C–X bond formation upon exposure to a panel of one- and two-electron oxidants is reported. High selectivity for C(sp2)–N bond formation is observed in all cases,… read more here.
Keywords: reactivity nnn; bond formation; bond; aryl complex ... See more keywords
Does Reduction-Induced Isomerization of a Uranium(III) Aryl Complex Proceed via C-H Oxidative Addition and Reductive Elimination across the Uranium(II/IV) Redox Couple?
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DOI: 10.1021/acs.inorgchem.2c01563
Abstract: Reaction of the uranium(III) bis(amidinate) aryl complex {TerphC(NiPr)2}2U(Terph) (2, where Terph = 4,4″-di-tert-butyl-m-terphenyl-2'-yl) with a strong reductant enabled isolation of isomeric uranium(III) bis(amidinate) aryl product {TerphC(NiPr)2}2U(Terph*) (3, where Terph* = 4,4″-di-tert-butyl-m-terphenyl-4'-yl). In terms of connectivity,… read more here.
Keywords: oxidative addition; addition reductive; aryl complex; uranium ... See more keywords