Diazo compounds and palladium-aryl complexes: trapping the elusive carbene migratory insertion organometallic products.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02775e
Abstract: The reactions of Pd-aryl complexes with diazo compounds N2CH-CHCHPh and N2CHPh allowed us to isolate the organometallic products formed right after the migratory insertion of a non-stabilized CHR carbene into the Pd-aryl bond. η3-Allylic and… read more here.
Keywords: migratory insertion; aryl complexes; diazo compounds; organometallic products ... See more keywords
Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media
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DOI: 10.1039/d3sc00373f
Abstract: Among the known types of non-covalent interactions with a Au(i) metal center, Au(i) involving halogen bonding (XB) remains a rare phenomenon that has not been studied systematically. Herein, using five N-heterocyclic carbene (NHC) Au(i) aryl… read more here.
Keywords: heterocyclic carbene; involving halogen; aryl complexes; halogen bonding ... See more keywords
Reactions of POP-pincer rhodium(I)-aryl complexes with small molecules: coordination flexibility of the ether diphosphine
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DOI: 10.1139/cjc-2020-0061
Abstract: Reactions of the aryl complexes Rh(aryl){κ3-P,O,P-[xant(PiPr2)2]} (1; aryl = 3,5-Me2C6H3 (a), C6H5 (b), 3,5-Cl2C6H3 (c), 3-FC6H4 (d); xant(PiPr2)2 = 9,9-dimethyl-4,5-bis-(diisopropylphosphino)xanth... read more here.
Keywords: pincer rhodium; rhodium aryl; pop pincer; aryl complexes ... See more keywords