Visible light mediated synthesis of 4-aryl-1,2-dihydronaphthalene derivatives via single-electron oxidation or MHAT from methylenecyclopropanes
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DOI: 10.1039/d0qo00853b
Abstract: We report a direct single-electron oxidation of methylenecyclopropanes (MCPs) for the rapid construction of 4-aryl-1,2-dihydronaphthalene derivatives by merging visible light photoredox catalysis and cobalt catalysis. In MeCN with Et3N·3HF (1.0 equiv.), the fluorination of MCPs… read more here.
Keywords: single electron; dihydronaphthalene derivatives; visible light; electron oxidation ... See more keywords