LAUSR

Aryl Fluorosulfate Trapped Staudinger Reduction.

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0 Published in 2017 at "Organic letters"

DOI: 10.1021/acs.orglett.7b00406

Abstract: A chemoselective Staudinger reduction/sulfur(VI) fluoride exchange cascade has been developed to join two chemical segments through an aryl sulfamate ester (RNH-SO2-OAr) linkage. Aryl fluorosulfate is exploited in this work as the first tetrahedral electrophilic trap… read more here.

Keywords: trapped staudinger; staudinger reduction; fluorosulfate trapped; aryl fluorosulfate ... See more keywords