Palladium(II)-Catalyzed Regioselective Hydroesterification of 1,3-Conjugated Enynes with Aryl Formates.
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DOI: 10.1021/acs.orglett.2c04103
Abstract: An effective Pd-catalyzed regioselective hydroesterification of 1,3-conjugated enynes with aryl formates was developed. Under the Pd-CyDPEphos catalytic system, the conjugated enynes reacted with phenyl formates and selectively provided the 2-ester-substituted 1,3-dienes in good yields with… read more here.
Keywords: aryl formates; regioselective hydroesterification; hydroesterification conjugated; conjugated enynes ... See more keywords
Pd-Catalyzed Hydroesterification of Vinyl Cyclopropanes with Aryl Formates
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DOI: 10.1039/d5qo00634a
Abstract: A Pd-catalyzed hydroesterification of vinyl cyclopropanes with aryl formates is described. A wide variety of cyclopropane-containing or ring-opening carboxylic esters can be obtained in good yields under mild reaction conditions.... read more here.
Keywords: cyclopropanes aryl; catalyzed hydroesterification; hydroesterification vinyl; aryl formates ... See more keywords
Palladium-Catalyzed Esterification of Aryl Fluorosulfates with Aryl Formates
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DOI: 10.3390/molecules29091991
Abstract: An efficient palladium-catalyzed carbonylation of aryl fluorosulfates with aryl formates for the facile synthesis of esters was developed. The cross-coupling reactions proceeded effectively in the presence of a palladium catalyst, phosphine ligand, and triethylamine in… read more here.
Keywords: palladium catalyzed; aryl formates; aryl; aryl fluorosulfates ... See more keywords