Synthesis of complex aryl MIDA boronates by Rh-catalyzed [2+2+2] cycloaddition.
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DOI: 10.1039/d3cc00761h
Abstract: A Rh-catalyzed [2+2+2] cycloaddition approach for the synthesis of BMIDA-functionalized arenes is reported. The developed method overcomes the long-standing reactivity problems associated with internal alkynes and allows access to highly functionalized borylated benzene scaffolds. The… read more here.
Keywords: synthesis complex; catalyzed cycloaddition; synthesis; aryl mida ... See more keywords