Tunable Gold‐catalyzed Reactions of Propargyl Alcohols and Aryl Nucleophiles
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DOI: 10.1002/open.202200030
Abstract: Abstract Gold‐catalyzed transformations of 1,3‐diarylpropargyl alcohols and various aryl nucleophiles were studied. Selective tunable synthetic methods were developed for 1,1,3‐triarylallenes, diaryl‐indenes and tetraaryl‐allyl target products by C3 nucleophilic substitution and subsequent intra‐ or intermolecular hydroarylation,… read more here.
Keywords: tunable gold; diaryl indenes; aryl nucleophiles; catalyzed reactions ... See more keywords
Synthesis of Benzhydryl-Substituted Amines by Silanolate-Mediated Aldimine Arylation with Functionalized Aryl Nucleophiles Released from Diazene-Based Reagents.
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DOI: 10.1021/acs.orglett.2c03798
Abstract: A transition-metal-free protocol for the arylation of N-phenyl- and N-benzoyl-substituted, benzaldehyde-derived imine derivatives with functionalized aryl pronucleophiles is reported. The aryl nucleophiles are released from silicon-protected aryl-substituted diazenes by desilylation with potassium trimethylsilanolate concomitant with… read more here.
Keywords: synthesis benzhydryl; functionalized aryl; aryl nucleophiles; benzhydryl substituted ... See more keywords