First principles details into the grafting of aryl radicals onto the free-standing and borophene/Ag(1 1 1) surfaces
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Physics"
DOI: 10.1016/j.chemphys.2021.111124
Abstract: Abstract We suspect that a possible interaction of the aryl radicals with the borophene surface is important for the stabilization and functionalization of the surface. Therefore, the grafting of multiple para-substituted aryl radicals onto the… read more here.
Keywords: aryl radicals; radicals onto; first principles; bond ... See more keywords
Generation of Aryl Radicals from Aryl Hydrazines via Catalytic Iodine in Air: Arylation of Substituted 1,4-Naphthoquinones
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DOI: 10.1021/acsomega.9b04014
Abstract: Arylated building blocks or heterocycles are key to myriad applications, including pharmaceutical drug discovery, materials sciences, and many more. Herein, we have reported a mild and efficient strategy for generation of aryl radicals by reacting… read more here.
Keywords: generation aryl; aryl radicals; catalytic iodine; aryl hydrazines ... See more keywords
Iron-mediated site-selective oxidative C–H/C–H cross-coupling of aryl radicals with quinones: synthesis of β-secretase-1 inhibitor B and related arylated quinones
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00623k
Abstract: Phenoxy radicals were converted intoparasite selectiveC-aryl radicals and coupled with quinones, using an inexpensive FeCl3–K2S2O8system, to obtain several arylated quinones, in good to moderate yields. read more here.
Keywords: aryl radicals; selective oxidative; site selective; arylated quinones ... See more keywords
Transition-Metal-Free Synthesis of Unsymmetrical Diaryl Tellurides via SH2 Reaction of Aryl Radicals on Tellurium
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DOI: 10.3390/molecules27030809
Abstract: Although diaryl tellurides are parent organotellurium compounds, their synthesis methods, especially for unsymmetrical ones, are limited. This may be due to the instability of diaryl tellurides and their synthesis intermediates under reaction conditions. Radical reactions… read more here.
Keywords: reaction aryl; diaryl tellurides; aryl radicals; sh2 reaction ... See more keywords