Photoinduced transition-metal- and external-photosensitizer-free intramolecular aryl rearrangement via C(Ar)–O bond cleavage† †Electronic supplementary information (ESI) available. See DOI: 10.1039/d0sc01585g
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DOI: 10.1039/d0sc01585g
Abstract: “We report a protocol for photoinduced transition-metal- and external-photocatalyst-free intramolecular heteroaryl/aryl rearrangement reactions of 2-heteroaryl/aryloxybenzaldehydes. The protocol was compatible with a variety of functionalities. read more here.
Keywords: transition metal; metal external; photoinduced transition; free intramolecular ... See more keywords
Nickel-catalyzed 1,4-aryl rearrangement of aryl N-benzylimidates via C-O and C-H bond cleavage.
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DOI: 10.1039/d2cc02355e
Abstract: We report herein that nickel-catalyzed reaction of aryl imidates bearing an N-benzyl group results in 1,4-migration of an O-aryl group via the cleavage of C-O and C-H bonds. This protocol allows for the benzylic C-H… read more here.
Keywords: cleavage; aryl; nickel catalyzed; catalyzed aryl ... See more keywords