Transition metal-free, chemoselective arylation of thioamides yielding aryl thioimidates or N-aryl thioamides.
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DOI: 10.1039/c8cc04795b
Abstract: Reactions of secondary thioamides with diaryliodonium salts under basic, transition metal-free conditions resulted in chemoselective S-arylation to provide aryl thioimidates in good to excellent yields. Equimolar amounts of thioamide, base and diaryliodonium salt were sufficient… read more here.
Keywords: metal free; aryl thioimidates; transition metal; chemoselective arylation ... See more keywords