Chromium-catalyzed olefination of arylaldehydes with haloforms assisted by 2,3,5,6-tetramethyl-N,N'-bis(trimethylsilyl)-1,4-dihydropyrazine.
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DOI: 10.1039/d2cc06104j
Abstract: Chromium-catalyzed olefination of arylaldehydes with haloforms was achieved using 2,3,5,6-tetramethyl-N,N'-bis(trimethylsilyl)-1,4-dihydropyrazine (1a) as an organic reducing agent, giving β-halostyrene derivatives in a trans-selective manner. The reaction required no metal powders, such as zinc and manganese, as… read more here.
Keywords: arylaldehydes haloforms; olefination arylaldehydes; chromium catalyzed; bis trimethylsilyl ... See more keywords