Palladium-Catalyzed Regioselective Arylalkenylation of Ynamides.
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DOI: 10.1021/acs.orglett.2c00197
Abstract: A cationic palladium-catalyzed arylalkenylation of ynamides is presented. The putative keteniminium arylpalladium intermediate likely dictates the regioselective carbopalladation of the ynamide to form a vinylpalladium species. The capture of this complex by the olefin yields… read more here.
Keywords: catalyzed regioselective; palladium catalyzed; regioselective arylalkenylation; arylalkenylation ynamides ... See more keywords