Synthesis and Photophysical Properties of 5-N-Arylamino-4-methylthiazoles Obtained from Direct C–H Arylations and Buchwald–Hartwig Aminations of 4-Methylthiazole
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DOI: 10.1021/acs.organomet.7b00128
Abstract: 5-N-Arylamino-4-methylthiazoles were synthesized from commercially available 4-methylthiazole in three consecutive steps: (i) direct Pd-catalyzed C–H arylations of the thiazole, (ii) bromination, and (iii) Pd-catalyzed Buchwald–Hartwig aminations. The resulting thiazoles showed the longest-wavelength absorption maxima at… read more here.
Keywords: arylamino methylthiazoles; buchwald hartwig; synthesis photophysical; hartwig aminations ... See more keywords