Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes
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DOI: 10.1021/acscatal.8b01753
Abstract: Despite extensive research on transition metal-catalyzed Fujiwara–Moritani type C–H olefinations, the alkenes used in these transformations are still mainly limited to active acrylate esters and styrenes. Selective aryl C–H olefination with electron-rich alkenes is recognized… read more here.
Keywords: rich alkenes; electron rich; dehydrogenative arylation; electron ... See more keywords
Non-directed C-H arylation of electron-deficient arenes by synergistic silver and Pd3 cluster catalysis.
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DOI: 10.1039/d2nr05825a
Abstract: Transition-metal clusters have attracted great attention in catalysis due to their unique reactivity and electronic properties, especially for novel substrate binding and activation modes at the bridging coordination sites of metal clusters. Although palladium complexes… read more here.
Keywords: non directed; catalysis; electron deficient; arylation electron ... See more keywords
Cu(II)-catalyzed N-arylation of electron-deficient NH-heterocycles ‘in-water’
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DOI: 10.1039/d3gc05163c
Abstract: Cu(II)-catalyzed N-arylation of electron-deficient NH-heterocycles is described ‘in-water’ at room temperature. A wide spectrum of substrate scope with respect to structural and electronic variation of NH-heterocycles plus arylboronic acids allows... read more here.
Keywords: arylation electron; deficient heterocycles; catalyzed arylation; electron deficient ... See more keywords