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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13586
Abstract: Pd(II)-catalyzed site-selective β- and γ-C(sp3)-H arylation of primary aldehydes is developed by rational design of L,X-type transient directing groups (TDG). External 2-pyridone ligands are identified to be crucial for the observed reactivity. By minimizing the…
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Keywords:
arylation primary;
selective sp3;
catalyzed site;
sp3 arylation ... See more keywords