Catalyst- and additive-free selective sulfonylation/cyclization of 1,6-enynes with arylazo sulfones leading to sulfonylated γ-butyrolactams
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DOI: 10.1016/j.cclet.2020.11.059
Abstract: Abstract A convenient and regioselective sulfonylation/cyclization of 1,6-enynes with arylazo sulfones has been developed to access a series of sulfonylated γ-butyrolactams. The present reaction could be efficiently conducted under catalyst- and additive-free conditions, in which… read more here.
Keywords: catalyst additive; enynes arylazo; cyclization enynes; sulfonylated butyrolactams ... See more keywords
Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01788
Abstract: The visible-light-driven preparation of (hetero)aryl stannanes was carried out under both photocatalyst- and metal-free conditions via irradiation of arylazo sulfones in the presence of hexaalkyldistannanes. The reaction shows a high efficiency and a wide substrates… read more here.
Keywords: arylstannanes arylazo; visible light; synthesis arylstannanes; light driven ... See more keywords
Visible-light-induced one-pot synthesis of sulfonic esters via multicomponent reaction of arylazo sulfones and alcohols
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DOI: 10.1039/d2ra02656b
Abstract: Sulfonic ester is a chemical structure common to many organic molecules, including biologically active compounds. Herein, a visible-light-induced synthetic method to prepare aryl sulfonic ester from arylazo sulfones was developed. In the present study, a… read more here.
Keywords: light induced; reaction; arylazo sulfones; one pot ... See more keywords
Synthesis of non-symmetric ortho-functionalized azoarenes through arylation of arylazo sulfones
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DOI: 10.1039/d5qo00932d
Abstract: A novel protocol for the arylation of arylazo sulfones with organomagnesiums for accessing non-symmetric ortho-functionalized azoarenes has been successfully developed. read more here.
Keywords: ortho functionalized; arylazo sulfones; non symmetric; arylation arylazo ... See more keywords